Study Calculating Equilibrium Concentrations in AP Chemistry with focused flashcards that help you recognize the idea, recall the key rule, and apply it in practice-style prompts.
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Flashcard 1: For the reaction CH4(g)+2O2(g)⇌CO2(g)+2H2O(g), write the Kc expression.
Answer: Kc=[CH4][O2]2[CO2][H2O]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 2: Calculate Kc for H2+I2⇌2HI with [H2]=1M, [I2]=1M, [HI]=2M.
Answer: Kc=14. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 3: State the effect of adding a reactant on the equilibrium position.
Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.
Flashcard 4: What is the effect of a catalyst on the equilibrium constant K?
Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or K.
Flashcard 5: Identify the equilibrium expression for the reaction N2(g)+3H2(g)⇌2NH3(g).
Answer: Kc=[N2][H2]3[NH3]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 6: State the relationship between Kp and Kc for gaseous reactions.
Answer: Kp=Kc(RT)Δn. Where Δn is moles of gaseous products minus gaseous reactants.
Flashcard 7: State the unit for Kc for the reaction aA+bB⇌cC+dD if c+d=a+b.
Answer: Unitless. When total moles of products equals total moles of reactants.
Flashcard 8: What happens to Kc of an exothermic reaction when temperature increases?
Answer: Kc decreases. Higher temperature opposes exothermic reactions, decreasing Kc.
Flashcard 9: Find Kc for the reaction 2A⇌B+C if [A]=0.5M, [B]=1M, [C]=1M.
Answer: Kc=0.521×1. Kc=[A]2[B][C]=0.521×1=4.
Flashcard 10: For the reaction 2NO(g)+O2(g)⇌2NO2(g), what is the Kp expression?
Answer: Kp=PNO2PO2PNO22. Products over reactants using partial pressures, raised to coefficients.
Flashcard 11: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?
Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.
Flashcard 12: For the endothermic reaction A⇌B, what is the effect of increasing temperature?
Answer: Shifts towards B. Higher temperature favors endothermic reactions (heat-absorbing direction).
Flashcard 13: For the reaction C(s)+CO2(g)⇌2CO(g), write the Kc expression.
Answer: Kc=[CO]2/[CO2]. Solid carbon is excluded, only gaseous species are included.
Flashcard 14: Given Kc=10 for A⇌B, find Kc for 2A⇌2B.
Answer: Kc=102. When reaction is doubled, equilibrium constant is squared.
Flashcard 15: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts towards NH3. Higher pressure favors the side with fewer gas molecules (2 vs 4).
Flashcard 16: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts towards NH3. Higher pressure favors the side with fewer gas molecules (2 vs 4).
Flashcard 17: Identify the equilibrium expression for CO(g)+Cl2(g)⇌COCl2(g).
Answer: Kc=[CO][Cl2][COCl2]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 18: What is the equilibrium constant expression for 2H2O2(aq)⇌2H2O(l)+O2(g)?
Answer: Kc=[O2]. Liquids are excluded from equilibrium expressions, only gases included.
Flashcard 19: State the Kc expression for the reaction C2H4(g)+H2(g)⇌C2H6(g).
Answer: Kc=[C2H4][H2][C2H6]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 20: What is the equilibrium expression for H2(g)+S(s)⇌H2S(g)?
Answer: Kc=[H2S]. Solids are excluded from equilibrium expressions, only gases included.
Flashcard 21: State the unit for Kc for the reaction aA+bB⇌cC+dD if c+d=a+b.
Answer: Unitless. When total moles of products equals total moles of reactants.
Flashcard 22: For 2NO2(g)⇌N2O4(g), what happens to Kc if temperature is increased?
Answer: Kc decreases. Higher temperature opposes exothermic reactions, decreasing Kc.
Flashcard 23: For the reaction H2(g)+I2(g)⇌2HI(g), find Kc if [HI]=2M, [H2]=1M, [I2]=1M.
Answer: Kc=4. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 24: For the reaction H2(g)+I2(g)⇌2HI(g), find Kc if [HI]=2M, [H2]=1M, [I2]=1M.
Answer: Kc=4. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 25: What is the effect of a catalyst on the equilibrium constant K?
Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or K.
Flashcard 26: What is the equilibrium expression for H2(g)+S(s)⇌H2S(g)?
Answer: Kc=[H2S]. Solids are excluded from equilibrium expressions, only gases included.
Flashcard 27: For the reaction CH4(g)+2O2(g)⇌CO2(g)+2H2O(g), write the Kc expression.
Answer: Kc=[CH4][O2]2[CO2][H2O]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 28: If Kc=1.5 for the reaction A⇌B, what is the value of Kc for B⇌A?
Answer: Kc=1.51. For the reverse reaction, Kc becomes the reciprocal of the original.
Flashcard 29: If Kc=1.5 for the reaction A⇌B, what is the value of Kc for B⇌A?
Answer: Kc=1.51. For the reverse reaction, Kc becomes the reciprocal of the original.
Flashcard 30: State the relationship between Kp and Kc for gaseous reactions.
Answer: Kp=Kc(RT)Δn. Where Δn is moles of gaseous products minus gaseous reactants.
Flashcard 31: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?
Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.
Flashcard 32: What is the expression for the equilibrium constant Kc for the reaction aA+bB⇌cC+dD?
Answer: Kc=[A]a[B]b[C]c[D]d. Products in numerator raised to their coefficients, reactants in denominator.
Flashcard 33: For the reaction PCl5(g)⇌PCl3(g)+Cl2(g), what is the effect of decreasing temperature?
Answer: Shifts towards PCl5. Lower temperature favors the exothermic direction (heat-producing side).
Flashcard 34: For the reaction 2NO(g)+O2(g)⇌2NO2(g), what is the Kp expression?
Answer: Kp=PNO2PO2PNO22. Products over reactants using partial pressures, raised to coefficients.
Flashcard 35: For the reaction H2(g)+I2(g)⇌2HI(g), find Kc if [HI]=2M, [H2]=1M, [I2]=1M.
Answer: Kc=4. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 36: What is the effect of adding a product on the position of equilibrium?
Answer: Shifts left to form more reactants. Le Chatelier's principle: system responds by consuming the added product.
Flashcard 37: Calculate Kc for H2+I2⇌2HI with [H2]=1M, [I2]=1M, [HI]=2M.
Answer: Kc=14. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 38: State the Kc expression for the reaction C2H4(g)+H2(g)⇌C2H6(g).
Answer: Kc=[C2H4][H2][C2H6]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 39: Identify the equilibrium expression for CO(g)+Cl2(g)⇌COCl2(g).
Answer: Kc=[CO][Cl2][COCl2]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 40: For A⇌B+C, if Kc=2, what is Kc for B+C⇌A?
Answer: Kc=21. For the reverse reaction, Kc becomes the reciprocal of the original.
Flashcard 41: Find Kc for A⇌2B if [A]=1M, [B]=0.5M at equilibrium.
Answer: Kc=10.52. Kc=[A][B]2=10.52=0.25.
Flashcard 42: Given Kc=10 for A⇌B, find Kc for 2A⇌2B.
Answer: Kc=102. When reaction is doubled, equilibrium constant is squared.
Flashcard 43: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).
Flashcard 44: State the unit for Kc for the reaction aA+bB⇌cC+dD if c+d=a+b.
Answer: Unitless. When total moles of products equals total moles of reactants.
Flashcard 45: For the reaction CH4(g)+2O2(g)⇌CO2(g)+2H2O(g), write the Kc expression.
Answer: Kc=[CH4][O2]2[CO2][H2O]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 46: For the reaction 2SO2(g)+O2(g)⇌2SO3(g), what is the expression for Kp?
Answer: Kp=PSO22PO2PSO32. Products over reactants using partial pressures, raised to coefficients.
Flashcard 47: State the effect of adding a reactant on the equilibrium position.
Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.
Flashcard 48: Identify the equilibrium expression for CO(g)+Cl2(g)⇌COCl2(g).
Answer: Kc=[CO][Cl2][COCl2]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 49: State the Kc expression for the reaction C2H4(g)+H2(g)⇌C2H6(g).
Answer: Kc=[C2H4][H2][C2H6]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 50: If Kc=1.5 for the reaction A⇌B, what is the value of Kc for B⇌A?
Answer: Kc=1.51. For the reverse reaction, Kc becomes the reciprocal of the original.
Flashcard 51: For N2O4(g)⇌2NO2(g), how does increasing pressure affect equilibrium?
Answer: Shifts towards N2O4. Higher pressure favors the side with fewer gas molecules (1 vs 2).
Flashcard 52: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?
Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.
Flashcard 53: State the relationship between Kp and Kc for gaseous reactions.
Answer: Kp=Kc(RT)Δn. Where Δn is moles of gaseous products minus gaseous reactants.
Flashcard 54: For N2O4(g)⇌2NO2(g), how does increasing pressure affect equilibrium?
Answer: Shifts towards N2O4. Higher pressure favors the side with fewer gas molecules (1 vs 2).
Flashcard 55: For the reaction 2NO(g)+O2(g)⇌2NO2(g), what is the Kp expression?
Answer: Kp=PNO2PO2PNO22. Products over reactants using partial pressures, raised to coefficients.
Flashcard 56: If [N2]=2M, [H2]=1M, [NH3]=0.5M, find Qc for N2+3H2⇌2NH3.
Answer: Qc=2×130.52. Qc=[N2][H2]3[NH3]2=2×130.52=20.25.
Flashcard 57: For the reaction 2SO2(g)+O2(g)⇌2SO3(g), what is the expression for Kp?
Answer: Kp=PSO22PO2PSO32. Products over reactants using partial pressures, raised to coefficients.
Flashcard 58: What is the equilibrium expression for H2(g)+S(s)⇌H2S(g)?
Answer: Kc=[H2S]. Solids are excluded from equilibrium expressions, only gases included.
Flashcard 59: How does a decrease in the concentration of O2 affect equilibrium in 2SO2+O2⇌2SO3?
Answer: Shifts left. Removing reactant shifts equilibrium to replace it via reverse reaction.
Flashcard 60: Determine the equilibrium constant Kc for the reaction 2NO2(g)⇌N2O4(g) given [NO2]=0.5M, [N2O4]=0.2M.
Answer: Kc=0.8. Kc=[NO2]2[N2O4]=0.520.2=0.8.
Flashcard 61: What is the effect of increasing temperature on the equilibrium position of an exothermic reaction?
Answer: Shifts towards reactants. Higher temperature opposes exothermic reactions, favoring the reverse direction.
Flashcard 62: Calculate Kc for H2+I2⇌2HI with [H2]=1M, [I2]=1M, [HI]=2M.
Answer: Kc=14. Kc=[H2][I2][HI]2=1×122=4.
Flashcard 63: State the effect of a temperature decrease on an endothermic reaction's equilibrium position.
Answer: Shifts towards reactants. Lower temperature opposes endothermic reactions, favoring reactant formation.
Flashcard 64: Identify the expression for Kc for H2O(l)⇌H+(aq)+OH−(aq).
Answer: Kw=[H+][OH−]. Auto-ionization of water uses Kw notation for the equilibrium constant.
Flashcard 65: What is the equilibrium constant expression for 2H2O2(aq)⇌2H2O(l)+O2(g)?
Answer: Kc=[O2]. Liquids are excluded from equilibrium expressions, only gases included.
Flashcard 66: If [N2]=2M, [H2]=1M, [NH3]=0.5M, find Qc for N2+3H2⇌2NH3.
Answer: Qc=2×130.52. Qc=[N2][H2]3[NH3]2=2×130.52=20.25.
Flashcard 67: For the endothermic reaction A⇌B, what is the effect of increasing temperature?
Answer: Shifts towards B. Higher temperature favors endothermic reactions (heat-absorbing direction).
Flashcard 68: Find Kc for the reaction 2A⇌B+C if [A]=0.5M, [B]=1M, [C]=1M.
Answer: Kc=0.521×1. Kc=[A]2[B][C]=0.521×1=4.
Flashcard 69: What is the effect of adding a product on the position of equilibrium?
Answer: Shifts left to form more reactants. Le Chatelier's principle: system responds by consuming the added product.
Flashcard 70: Identify the expression for Kc for H2O(l)⇌H+(aq)+OH−(aq).
Answer: Kw=[H+][OH−]. Auto-ionization of water uses Kw notation for the equilibrium constant.
Flashcard 71: Which factor does not affect the value of the equilibrium constant K?
Answer: Concentration of reactants or products. K depends only on temperature, not concentrations at equilibrium.
Flashcard 72: Which factor does not affect the value of the equilibrium constant K?
Answer: Concentration of reactants or products. K depends only on temperature, not concentrations at equilibrium.
Flashcard 73: For 2NO2(g)⇌N2O4(g), what happens to Kc if temperature is increased?
Answer: Kc decreases. Higher temperature opposes exothermic reactions, decreasing Kc.
Flashcard 74: State the effect of adding a reactant on the equilibrium position.
Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.
Flashcard 75: For 2NO2(g)⇌N2O4(g), what happens to Kc if temperature is increased?
Answer: Kc decreases. Higher temperature opposes exothermic reactions, decreasing Kc.
Flashcard 76: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).
Flashcard 77: What is the effect of a catalyst on the equilibrium constant K?
Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or K.
Flashcard 78: State the effect of adding a reactant on the equilibrium position.
Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.
Flashcard 79: For the reaction 2SO2(g)+O2(g)⇌2SO3(g), what is the expression for Kp?
Answer: Kp=PSO22PO2PSO32. Products over reactants using partial pressures, raised to coefficients.
Flashcard 80: For N2O4(g)⇌2NO2(g), how does increasing pressure affect equilibrium?
Answer: Shifts towards N2O4. Higher pressure favors the side with fewer gas molecules (1 vs 2).
Flashcard 81: For the reaction C(s)+CO2(g)⇌2CO(g), write the Kc expression.
Answer: Kc=[CO]2/[CO2]. Solid carbon is excluded, only gaseous species are included.
Flashcard 82: For N2O4(g)⇌2NO2(g), how does increasing pressure affect equilibrium?
Answer: Shifts towards N2O4. Higher pressure favors the side with fewer gas molecules (1 vs 2).
Flashcard 83: Identify the expression for Kc for H2O(l)⇌H+(aq)+OH−(aq).
Answer: Kw=[H+][OH−]. Auto-ionization of water uses Kw notation for the equilibrium constant.
Flashcard 84: What is the equilibrium constant expression for 2H2O2(aq)⇌2H2O(l)+O2(g)?
Answer: Kc=[O2]. Liquids are excluded from equilibrium expressions, only gases included.
Flashcard 85: What is the equilibrium expression for H2(g)+S(s)⇌H2S(g)?
Answer: Kc=[H2S]. Solids are excluded from equilibrium expressions, only gases included.
Flashcard 86: What is the effect of increasing temperature on the equilibrium position of an exothermic reaction?
Answer: Shifts towards reactants. Higher temperature opposes exothermic reactions, favoring the reverse direction.
Flashcard 87: Identify the equilibrium expression for the reaction N2(g)+3H2(g)⇌2NH3(g).
Answer: Kc=[N2][H2]3[NH3]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 88: Which factor does not affect the value of the equilibrium constant K?
Answer: Concentration of reactants or products. K depends only on temperature, not concentrations at equilibrium.
Flashcard 89: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts towards NH3. Higher pressure favors the side with fewer gas molecules (2 vs 4).
Flashcard 90: Find Kc for the reaction 2A⇌B+C if [A]=0.5M, [B]=1M, [C]=1M.
Answer: Kc=0.521×1. Kc=[A]2[B][C]=0.521×1=4.
Flashcard 91: If [N2]=2M, [H2]=1M, [NH3]=0.5M, find Qc for N2+3H2⇌2NH3.
Answer: Qc=2×130.52. Qc=[N2][H2]3[NH3]2=2×130.52=20.25.
Flashcard 92: Identify the equilibrium expression for the reaction N2(g)+3H2(g)⇌2NH3(g).
Answer: Kc=[N2][H2]3[NH3]2. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 93: What is the effect of a catalyst on the equilibrium constant K?
Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or K.
Flashcard 94: Determine the equilibrium constant Kc for the reaction 2NO2(g)⇌N2O4(g) given [NO2]=0.5M, [N2O4]=0.2M.
Answer: Kc=0.8. Kc=[NO2]2[N2O4]=0.520.2=0.8.
Flashcard 95: What is the equilibrium constant expression for 2H2O2(aq)⇌2H2O(l)+O2(g)?
Answer: Kc=[O2]. Liquids are excluded from equilibrium expressions, only gases included.
Flashcard 96: State the Kc expression for the reaction C2H4(g)+H2(g)⇌C2H6(g).
Answer: Kc=[C2H4][H2][C2H6]. Products over reactants, each raised to their stoichiometric coefficients.
Flashcard 97: Find Kc for A⇌2B if [A]=1M, [B]=0.5M at equilibrium.
Answer: Kc=10.52. Kc=[A][B]2=10.52=0.25.
Flashcard 98: Determine the equilibrium constant Kc for the reaction 2NO2(g)⇌N2O4(g) given [NO2]=0.5M, [N2O4]=0.2M.
Answer: Kc=0.8. Kc=[NO2]2[N2O4]=0.520.2=0.8.
Flashcard 99: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)⇌2NH3(g)?
Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).
Flashcard 100: If Kc=1.5 for the reaction A⇌B, what is the value of Kc for B⇌A?
Answer: Kc=1.51. For the reverse reaction, Kc becomes the reciprocal of the original.