AP Chemistry › Reaction Types
Which of the following is what determines the strength of an acid?
The Ka
The Kb
Its physical state
How many bonds the central atom makes
Electronegativity values
The Ka is the acid dissociation constant, and thus it is what determines how strong the acid is. Stronger acids dissociate to a greater extent and produce lower pH values.
Consider the following reaction:
What is the oxidizing agent, and what is the reducing agent?
Silver is the oxidizing agent and copper is the reducing agent
Silver is the reducing agent and copper is the oxidizing agent
Silver is the oxidizing agent and there is no reducing agent
No redox chemistry occurs
Silver is the reducing agent and there is no oxidizing agent
Let's break down the reaction into two separate reactions:
and
We can see that copper loses electrons, while silver gains electrons. Recall that oxidation is loss and reduction is gain, with regard to electrons. Copper is oxidized and silver is reduced.
However, this question asks for the oxidizing agent and reducing agent. Recall that the oxidizing agent is reduced, while the reducing agent is oxidized. Since copper is oxidized, it is the reducing agent. Similarly, since silver is reduced, it is the oxidizing agent.
In the following reaction, which compound is being oxidized?
Copper
Sulfur
Hydrogen
Nitrate
No oxidation takes place
Hydrogen doesn't change. Cu2+ doesn't change (partnered with S2- then with SO42-). Sulfur goes from S2- and S6+(paired with 6 O2- with a 2– charge), showing an oxidation. Nitrogen goes from N5+ to N2+ meaning it was reduced.
In the following reaction, which compound is being oxidized?
Copper
Sulfur
Hydrogen
Nitrate
No oxidation takes place
Hydrogen doesn't change. Cu2+ doesn't change (partnered with S2- then with SO42-). Sulfur goes from S2- and S6+(paired with 6 O2- with a 2– charge), showing an oxidation. Nitrogen goes from N5+ to N2+ meaning it was reduced.
How many electrons are involved in the following reaction?
1 e-
2 e-
4 e-
5 e-
10 e-
The common factor between 2 e- and 5 e- is 10. Therefore the number of electrons involved is 10 e-.
The following ReDox reaction takes place in acidic solution:
Fe2+ + Cr2O72– → Fe3+ + Cr3+
What is the sum of coefficients in this redox reaction?
36
35
34
33
37
When you balance the redox reaction in acidic conditons, there are 6Fe2+, 1 Cr2O72–, 14 H+, 6 Fe3+, 2 Cr3+, and 7 H2O. Don't forget to add the 1 in front of the Cr2O72–
Which of the following is what determines the strength of an acid?
The Ka
The Kb
Its physical state
How many bonds the central atom makes
Electronegativity values
The Ka is the acid dissociation constant, and thus it is what determines how strong the acid is. Stronger acids dissociate to a greater extent and produce lower pH values.
If you have a solution that consists of a monoprotic acid (HA), with a pKa of 4.1 and at a pH of 5.8, what is the predominant species present?
HA
A-
H2A+
H3O+
Equal amounts of acid and conjugate base are present.
Since pH > pKA, the deprotonated form of the acid is predominant.
Determine the pH of a solution that is .
Since is a strong acid, the concentration of
is equal to the concentration of the acid itself.
Thus, .
Recall how to find the pH of a solution:
Plug in the given hydronium ion concentration to find the pH of the given solution.
Remember to maintain the correct number of significant figures.
Which of the following will increase the pH of an buffer solution?
I. Removing carbonic acid
II. Adding sodium bicarbonate
Both I and II
I only
II only
Neither of these options
To answer this question we need to look at the reaction below:
An increase in the pH will result in a decrease in the concentration of hydrogen ions (). Using Le Chatelier’s principle we can find out which answer choices will decrease
.
Removing carbonic acid will decrease the concentration of . To maintain equilibrium, the reaction will shift to the left and make more reactants from products; therefore, there will be a decrease in the
and an increase in pH.
Recall that salts like sodium bicarbonate, or , will dissociate in water and form ions. Sodium bicarbonate will form sodium (
) and bicarbonate (
) ions. This side reaction will result in an increase in the bicarbonate ion concentration. Le Chatelier’s principle will shift the equilibrium of the given reaction to the left and, therefore, decrease the
. Adding sodium bicarbonate will increase the pH.