Reaction Types

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Questions 1 - 10
1

Which of the following is what determines the strength of an acid?

The Ka

The Kb

Its physical state

How many bonds the central atom makes

Electronegativity values

Explanation

The Ka is the acid dissociation constant, and thus it is what determines how strong the acid is. Stronger acids dissociate to a greater extent and produce lower pH values.

2

Consider the following reaction:

Cu_{(s)}+2Ag^{+}{(aq)}\rightarrow Cu^{2+}{(aq)}+2Ag_{(s)}

What is the oxidizing agent, and what is the reducing agent?

Silver is the oxidizing agent and copper is the reducing agent

Silver is the reducing agent and copper is the oxidizing agent

Silver is the oxidizing agent and there is no reducing agent

No redox chemistry occurs

Silver is the reducing agent and there is no oxidizing agent

Explanation

Let's break down the reaction into two separate reactions:

Cu_{(s)}\rightarrow Cu^{2+}_{(aq)}+2e^- and

2Ag^+{(aq)}+2e^- \rightarrow 2Ag{(s)}

We can see that copper loses electrons, while silver gains electrons. Recall that oxidation is loss and reduction is gain, with regard to electrons. Copper is oxidized and silver is reduced.

However, this question asks for the oxidizing agent and reducing agent. Recall that the oxidizing agent is reduced, while the reducing agent is oxidized. Since copper is oxidized, it is the reducing agent. Similarly, since silver is reduced, it is the oxidizing agent.

3

In the following reaction, which compound is being oxidized?

Copper

Sulfur

Hydrogen

Nitrate

No oxidation takes place

Explanation

Hydrogen doesn't change. Cu2+ doesn't change (partnered with S2- then with SO42-). Sulfur goes from S2- and S6+(paired with 6 O2- with a 2– charge), showing an oxidation. Nitrogen goes from N5+ to N2+ meaning it was reduced.

4

In the following reaction, which compound is being oxidized?

Copper

Sulfur

Hydrogen

Nitrate

No oxidation takes place

Explanation

Hydrogen doesn't change. Cu2+ doesn't change (partnered with S2- then with SO42-). Sulfur goes from S2- and S6+(paired with 6 O2- with a 2– charge), showing an oxidation. Nitrogen goes from N5+ to N2+ meaning it was reduced.

5

How many electrons are involved in the following reaction?

1 e-

2 e-

4 e-

5 e-

10 e-

Explanation

01

The common factor between 2 e- and 5 e- is 10. Therefore the number of electrons involved is 10 e-.

6

The following ReDox reaction takes place in acidic solution:

Fe2+ + Cr2O72– → Fe3+ + Cr3+

What is the sum of coefficients in this redox reaction?

36

35

34

33

37

Explanation

When you balance the redox reaction in acidic conditons, there are 6Fe2+, 1 Cr2O72–, 14 H+, 6 Fe3+, 2 Cr3+, and 7 H2O. Don't forget to add the 1 in front of the Cr2O72–

7

Which of the following is what determines the strength of an acid?

The Ka

The Kb

Its physical state

How many bonds the central atom makes

Electronegativity values

Explanation

The Ka is the acid dissociation constant, and thus it is what determines how strong the acid is. Stronger acids dissociate to a greater extent and produce lower pH values.

8

If you have a solution that consists of a monoprotic acid (HA), with a pKa of 4.1 and at a pH of 5.8, what is the predominant species present?

HA

A­-

H2A+

H3O+

Equal amounts of acid and conjugate base are present.

Explanation

Since pH > pKA, the deprotonated form of the acid is predominant.

9

Determine the pH of a solution that is .

Explanation

Since is a strong acid, the concentration of is equal to the concentration of the acid itself.

Thus, .

Recall how to find the pH of a solution:

Plug in the given hydronium ion concentration to find the pH of the given solution.

Remember to maintain the correct number of significant figures.

10

Which of the following will increase the pH of an buffer solution?

I. Removing carbonic acid

II. Adding sodium bicarbonate

Both I and II

I only

II only

Neither of these options

Explanation

To answer this question we need to look at the reaction below:

An increase in the pH will result in a decrease in the concentration of hydrogen ions (). Using Le Chatelier’s principle we can find out which answer choices will decrease .

Removing carbonic acid will decrease the concentration of . To maintain equilibrium, the reaction will shift to the left and make more reactants from products; therefore, there will be a decrease in the and an increase in pH.

Recall that salts like sodium bicarbonate, or , will dissociate in water and form ions. Sodium bicarbonate will form sodium () and bicarbonate () ions. This side reaction will result in an increase in the bicarbonate ion concentration. Le Chatelier’s principle will shift the equilibrium of the given reaction to the left and, therefore, decrease the . Adding sodium bicarbonate will increase the pH.

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