Organic Chemistry › Hydrocarbon Reactants
The stereochemical pathway for the hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via __________.
syn addition
formation of a bridged carbocation
anti addition
anti-Markovnikov addition
Markovnikov addition
Hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via syn addition.
It is important to note the three main types of reactions for alkenes. The first type of reaction is a 2-step mechanism in which the electrophile attacks the carbocation nucleophile. This can yield syn or anti products. The second type of reaction is a 2-step mechanism that forms a bridged carbocation as the intermediate. This can yield only anti products. The third and last type of reaction is a 1-step addition. This can only yield syn products.
An example of the third type of reaction is the addition of a hydrogen with palladium, platinum, or nickel as demonstrated in the picture.
The stereochemical pathway for the hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via __________.
syn addition
formation of a bridged carbocation
anti addition
anti-Markovnikov addition
Markovnikov addition
Hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via syn addition.
It is important to note the three main types of reactions for alkenes. The first type of reaction is a 2-step mechanism in which the electrophile attacks the carbocation nucleophile. This can yield syn or anti products. The second type of reaction is a 2-step mechanism that forms a bridged carbocation as the intermediate. This can yield only anti products. The third and last type of reaction is a 1-step addition. This can only yield syn products.
An example of the third type of reaction is the addition of a hydrogen with palladium, platinum, or nickel as demonstrated in the picture.
Predict the major product of the given reaction.
II
I
III
IV
None of these
Reaction of an alkene with osmium tetroxide results in syn addition of to hydroxyl groups across the double bond, resulting in a 1,2-diol. The correct answer is the option in which hydroxide groups are added to the previously double-bonded carbons on the same side of the ring. The correct answer is compound II.
Predict the product of the chemical reaction given.
The reaction given is called a Markovnikov's addition reaction. This is a regiospecific reaction because only one orientation of the reaction occurs. It is an electrophilic addition reaction that involves the reaction of a halogenic acid such as or
with an alkene. The hydrogen bonds to the carbon with the less alkyl groups bonded to the organic compound and the halogen ion bonds to the carbon with more alkyl substituents. Therefore the answer is:
Predict the product of the chemical reaction given.
The reaction given is called a Markovnikov's addition reaction. This is a regiospecific reaction because only one orientation of the reaction occurs. It is an electrophilic addition reaction that involves the reaction of a halogenic acid such as or
with an alkene. The hydrogen bonds to the carbon with the less alkyl groups bonded to the organic compound and the halogen ion bonds to the carbon with more alkyl substituents. Therefore the answer is:
Which of the following would be the product of the reaction given?
Molecular bromine reacts with an alkene in the presence of water to yield a halohydrin product. Below is the mechanism for this reaction:
Predict the major product of the given reaction.
II
I
III
IV
None of these
Reaction of an alkene with osmium tetroxide results in syn addition of to hydroxyl groups across the double bond, resulting in a 1,2-diol. The correct answer is the option in which hydroxide groups are added to the previously double-bonded carbons on the same side of the ring. The correct answer is compound II.
Which of the following would be the product of the reaction given?
Molecular bromine reacts with an alkene in the presence of water to yield a halohydrin product. Below is the mechanism for this reaction:
What is the product of the chemical reaction given?
Hydroxylation of alkene compounds is called a hydration reaction. The reaction occurs in the presence of a strong acid catalyst to protonate the organic compound similar to Markovnikov's addition forming a carbocation as an intermediate. A water molecule nucleophilicly bonds to the carbocation intermediate. A proton is lost from the positively charged oxygen to a chloride ion yielding the alcohol product and regenerating the acid.
What is the major product of the reaction given?
Alkenes react with NBS (N-bromosuccinimide) in the presence of light to giving products in the position next to the double called the allylic position. Below is the mechanism for this reaction: