Hydrocarbon Reactants

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Organic Chemistry › Hydrocarbon Reactants

Questions 1 - 10
1

The stereochemical pathway for the hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via __________.

syn addition

formation of a bridged carbocation

anti addition

anti-Markovnikov addition

Markovnikov addition

Explanation

Hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via syn addition.

It is important to note the three main types of reactions for alkenes. The first type of reaction is a 2-step mechanism in which the electrophile attacks the carbocation nucleophile. This can yield syn or anti products. The second type of reaction is a 2-step mechanism that forms a bridged carbocation as the intermediate. This can yield only anti products. The third and last type of reaction is a 1-step addition. This can only yield syn products.

An example of the third type of reaction is the addition of a hydrogen with palladium, platinum, or nickel as demonstrated in the picture.

1

2

The stereochemical pathway for the hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via __________.

syn addition

formation of a bridged carbocation

anti addition

anti-Markovnikov addition

Markovnikov addition

Explanation

Hydrogenation of an alkene with a metal catalyst, such as platinum, occurs via syn addition.

It is important to note the three main types of reactions for alkenes. The first type of reaction is a 2-step mechanism in which the electrophile attacks the carbocation nucleophile. This can yield syn or anti products. The second type of reaction is a 2-step mechanism that forms a bridged carbocation as the intermediate. This can yield only anti products. The third and last type of reaction is a 1-step addition. This can only yield syn products.

An example of the third type of reaction is the addition of a hydrogen with palladium, platinum, or nickel as demonstrated in the picture.

1

3

Screen shot 2015 07 08 at 8.37.25 am

Predict the major product of the given reaction.

II

I

III

IV

None of these

Explanation

Reaction of an alkene with osmium tetroxide results in syn addition of to hydroxyl groups across the double bond, resulting in a 1,2-diol. The correct answer is the option in which hydroxide groups are added to the previously double-bonded carbons on the same side of the ring. The correct answer is compound II.

4

Screen shot 2015 12 17 at 10.46.32 pm

Predict the product of the chemical reaction given.

Screen shot 2015 12 17 at 10.47.24 pm

Screen shot 2015 12 17 at 10.48.49 pm

Screen shot 2015 12 17 at 10.49.50 pm

Screen shot 2015 12 17 at 10.50.48 pm

Explanation

The reaction given is called a Markovnikov's addition reaction. This is a regiospecific reaction because only one orientation of the reaction occurs. It is an electrophilic addition reaction that involves the reaction of a halogenic acid such as or with an alkene. The hydrogen bonds to the carbon with the less alkyl groups bonded to the organic compound and the halogen ion bonds to the carbon with more alkyl substituents. Therefore the answer is:Screen shot 2015 12 17 at 10.47.24 pm

5

Screen shot 2015 12 17 at 10.46.32 pm

Predict the product of the chemical reaction given.

Screen shot 2015 12 17 at 10.47.24 pm

Screen shot 2015 12 17 at 10.48.49 pm

Screen shot 2015 12 17 at 10.49.50 pm

Screen shot 2015 12 17 at 10.50.48 pm

Explanation

The reaction given is called a Markovnikov's addition reaction. This is a regiospecific reaction because only one orientation of the reaction occurs. It is an electrophilic addition reaction that involves the reaction of a halogenic acid such as or with an alkene. The hydrogen bonds to the carbon with the less alkyl groups bonded to the organic compound and the halogen ion bonds to the carbon with more alkyl substituents. Therefore the answer is:Screen shot 2015 12 17 at 10.47.24 pm

6

Screen shot 2015 12 29 at 8.22.26 pm

Which of the following would be the product of the reaction given?

Screen shot 2015 12 29 at 8.23.25 pm

Screen shot 2015 12 29 at 8.23.30 pm

Screen shot 2015 12 29 at 8.23.34 pm

Screen shot 2015 12 29 at 8.26.49 pm

Explanation

Molecular bromine reacts with an alkene in the presence of water to yield a halohydrin product. Below is the mechanism for this reaction:

Screen shot 2015 12 29 at 8.23.16 pm

7

Screen shot 2015 07 08 at 8.37.25 am

Predict the major product of the given reaction.

II

I

III

IV

None of these

Explanation

Reaction of an alkene with osmium tetroxide results in syn addition of to hydroxyl groups across the double bond, resulting in a 1,2-diol. The correct answer is the option in which hydroxide groups are added to the previously double-bonded carbons on the same side of the ring. The correct answer is compound II.

8

Screen shot 2015 12 29 at 8.22.26 pm

Which of the following would be the product of the reaction given?

Screen shot 2015 12 29 at 8.23.25 pm

Screen shot 2015 12 29 at 8.23.30 pm

Screen shot 2015 12 29 at 8.23.34 pm

Screen shot 2015 12 29 at 8.26.49 pm

Explanation

Molecular bromine reacts with an alkene in the presence of water to yield a halohydrin product. Below is the mechanism for this reaction:

Screen shot 2015 12 29 at 8.23.16 pm

9

Screen shot 2016 01 24 at 6.26.30 pm

What is the product of the chemical reaction given?

Screen shot 2016 01 24 at 6.26.58 pm

Screen shot 2016 01 24 at 6.27.03 pm

Screen shot 2016 01 24 at 6.27.07 pm

Screen shot 2016 01 24 at 6.27.11 pm

Explanation

Hydroxylation of alkene compounds is called a hydration reaction. The reaction occurs in the presence of a strong acid catalyst to protonate the organic compound similar to Markovnikov's addition forming a carbocation as an intermediate. A water molecule nucleophilicly bonds to the carbocation intermediate. A proton is lost from the positively charged oxygen to a chloride ion yielding the alcohol product and regenerating the acid.

Screen shot 2016 01 24 at 6.26.46 pm

10

Screen shot 2016 01 10 at 9.24.24 pm

What is the major product of the reaction given?

Screen shot 2016 01 10 at 9.25.14 pm

Screen shot 2016 01 10 at 9.26.29 pm

Screen shot 2016 01 10 at 9.26.33 pm

Screen shot 2016 01 10 at 9.26.39 pm

Explanation

Alkenes react with NBS (N-bromosuccinimide) in the presence of light to giving products in the position next to the double called the allylic position. Below is the mechanism for this reaction:

Screen shot 2016 01 19 at 4.57.28 am

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