AP Chemistry : Compounds and Molecules

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #1 : Nomenclature And Functional Groups

What is the name for the following polyatomic ion:  (also written )?

Possible Answers:

Carbon trihydrogen monocarbon dioxide

Acetate

Dichromate

Dicarbon trihydrogen dioxide

Oxalate

Correct answer:

Acetate

Explanation:

 (also written as ) is the formula for the acetate ion. Most polyatomic ions tend to follow certain naming trends, but acetate is one of the ions that does not follow those naming trends, so memorize this one since it shows up frequently in chemistry.

Example Question #1 : Organic Compounds

Which of the following is the alcohol functional group?

Possible Answers:

-OH

-NH2

-COH

-COOH

-OR

Correct answer:

-OH

Explanation:

The alcohol functional group is -OH

Example Question #41 : Compounds And Molecules

What is the most acidic functional group on the amino acid cysteine? Cysteine has the chemical formula C_3H_7NO_2S.

Possible Answers:

Alcohol

Amine

Carboxylic acid

Thiol

Hydrochloric acid

Correct answer:

Carboxylic acid

Explanation:

We know that by definition, all amino acids contain a carboxylic acid functional group (CO_2H), and an amino functional group (NH_2). Therefore the additional functional group can only contain sulfur and hydrogen.

The amino functional group is slightly basic, and the carboylic acid functional group is slightly acidic. The -SH functional group will also be acidic, but because sulfur and oxygen are in the same group on the periodic table, the -SH group will have similar acidic properties to an -OH group, and alcohols are less acidic than carboxylic acids.

Example Question #3 : Organic Compounds

Which of the following functional groups is an amide?

Possible Answers:

Correct answer:

Explanation:

Amides contain both oxygen and nitrogen in the functional group. The oxygen forms a double bond with a carbon, and the carbon bonds to a nitrogen. This forms the structure , where the nitrogen is also bound to the carbon.

is an alcohol functional group.

is an amine functional group.

is a carboxylic acid functional group.

is an aldehyde functional group.

Example Question #42 : Compounds And Molecules

Which one of the following organic functional groups does not contain a carbon-oxygen double bond?

Possible Answers:

Nitrile

Ketone

Aldehyde

Ester

Carboxylic acid

Correct answer:

Nitrile

Explanation:

A nitrile group contains a carbon-nitrogen triple bond, while all of the other groups contain a carbon-oxygen double bond.

Nitrile:

Ester:

Ketone:

Carboxylic acid:

Aldehyde:

Example Question #1 : Organic Compounds

Which of the following is an organic compound? 

Possible Answers:

Water

Oxygen

Magnesium fluoride

Sodium chloride

Glucose

Correct answer:

Glucose

Explanation:

An organic compound is typically defined as one that contains carbon. Though there some small exceptions to this rule (for example, cyanide is not considered organic), in general most compounds follow it. 

Though water, oxygen, and sodium chloride, may seem organic, they are not for they do not contain any covalent bonds to carbon. The only gievn compound that contains carbon is glucose, a sugar. 

Example Question #43 : Compounds And Molecules

A chemist is trying to find the identity of a compound. She knows that the compound has a molecular weight of , and also that it consists of  carbon,  hydrogen, and  oxygen by mass. What are the empirical and molecular formulas, respectively, for this compound?

Possible Answers:

It is impossible to tell without more information

Correct answer:

Explanation:

The simplest way to begin these types of problems is to assume that we are starting out with 100 grams of the sample compound. This allows us to simplify things, since we know the mass percentages of the elements that make up out unknown compound.

Next, we must convert amount of each element from grams into moles.

 

This gives us a formula of 

Now, we need to simplify this formula by dividing each of the terms by the greatest common denominator, 3.33, which gives us:

This is our empirical formula. To obtain the molecular formula, we must first find the mass of our empirical formula, which is .

Next, we need to divide the molecular weight of the compound by the empirical weight to obtain an integer of . Finally, we multiply the empirical formula by this integer in order to obtain the molecular formula, which is:

Example Question #1 : Lewis Diagrams

How many lone pairs of electrons exist on the following molecule?

BF3

Possible Answers:

0

11

9

1

10

Correct answer:

9

Explanation:

..            ..

:F — B —  F:         Boron can have a violated octet (6 e-) and each F has 3 lone pairs

..      |      ..          for a total of 9 pairs of unpaired electrons

        :F:

         .. 

Example Question #41 : Compounds And Bonding

Which of the following compounds contains an atom that does NOT satisfy the octet rule?

I.

II.

III.

IV.

Possible Answers:

II and III

I, II, and IV

I and II

IV only

I and IV

Correct answer:

I and IV

Explanation:

BCl3 only has six electrons around boron, while NO2 (with an odd number of electrons) would have only 7 electrons around the central nitrogen.

Example Question #2 : Molecules

Which of the following elements will have two unpaired valence electrons?

Possible Answers:

Neon

Beryllium

Carbon

Nitrogen

Fluorine

Correct answer:

Carbon

Explanation:

Lewis dot diagrams can help us keep track on how the valence electrons will disperse themselves among orbitals in the atom. When drawing these diagrams, it is important to keep two things in mind.

1. The s orbital will be filled before the p orbital begins to be filled.

2. Electrons will never pair in the same orbital if an orbital of equal energy is unoccupied.

Knowing these two facts, we can predict which of the following elements will have two unpaired electrons.

Fluorine will have seven valence electrons, meaning that only one orbital will not be completely filled.

Beryllium only has two valence electrons, but they will both be found in the 2s orbital, because it must be filled before the p orbitals can receive electrons.

Nitrogen will have five valence electrons, so two will be found in the 2s orbital. The other three will be present in their own p orbitals, meaning nitrogen has three unpaired electrons.

Neon will have eight valence electrons, fully filling the 2s and 2p orbitals. It will have no unpaires electrons. 

Carbon has one less valence electron than nitrogen, meaning that it will have two unpaired electrons in the p orbitals.

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