MCAT Physical : Stoichiometry and Analytical Chemistry

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #21 : Stoichiometry And Analytical Chemistry

Manganese forms a number of oxides, one of which is composed of 72% manganese by mass. Which of the following is the formula for this oxide?

Possible Answers:

\(\displaystyle \small Mn_{2}O_{7}\)

\(\displaystyle \small Mn_{2}O_{3}\)

\(\displaystyle \small Mn_{3}O_{4}\)

\(\displaystyle \small MnO\)

\(\displaystyle \small MnO_{2}\)

Correct answer:

\(\displaystyle \small Mn_{3}O_{4}\)

Explanation:

Given that the molar mass of oxygen is about 16g, and molar mass of manganese is about 55g, \(\displaystyle \small Mn_{3}O_{4}\) contains 165g of manganese and 64g of oxygen, for a total of 229g.

165g/229g = 0.72

So, the ratio of manganese to oxygen in this compound is 72% manganese by mass.

Example Question #22 : Stoichiometry And Analytical Chemistry

What is the mass percentage of carbon in glucose (C6H12O6)?

Possible Answers:

25%

It depends on the amount of glucose.

40%

96%

Correct answer:

40%

Explanation:

In order to find the mass percentage of an atom in a molecule, start by finding the total mass of one mole of the molecule. Glucose has 180 grams per mol.

\(\displaystyle 6(12)+12(1)+6(16)=180\)

Next, we determine the mass of the carbon atoms in one mole of the molecule. One carbon mole has a mass of 12 grams. Multiplied by the six carbon atoms in glucose gives a mass of 72 grams.

\(\displaystyle 6\frac{carbon\ atoms}{glucose}(12\frac{g\ C}{mol\ C})=72\frac{g\ carbon}{glucose}\)

Finally, we divide the mass of carbon by the mass of the molecule.

\(\displaystyle \small \frac{72}{180} = 0.4\)

So, 40% of glucose's mass is made up of carbon.

Example Question #23 : Stoichiometry And Analytical Chemistry

What is the mass percentage of aluminum in aluminum (III) oxide?

Possible Answers:

Correct answer:

Explanation:

Aluminum oxide has the formula \(\displaystyle Al_2O_3\).

Aluminum has a molecular weight of \(\displaystyle 27\frac{g}{mol}\), and oxygen has a weight of \(\displaystyle 16\frac{g}{mol}\). Using these values, we can calculate the molecular weight of aluminum oxide.

\(\displaystyle 27(2) + 16(3) = 102\frac{g}{mol}\)

The mass percentage is given by the mass of aluminum divided by the total molecular weight.

Example Question #23 : Molecular Weight, Molecular Formula, And Moles

What is the percentage by weight of sodium in sodium sulfate?

Possible Answers:

Correct answer:

Explanation:

Sodium sulfate is given by the formula:

\(\displaystyle Na_2SO_4\)

To find the percentage by weight, we will need to divide the mass of sodium in the molecule by the total molecular mass.

\(\displaystyle \text{mass Na}=2(23.0\frac{g}{mol})=46.0\frac{g}{mol}\)

\(\displaystyle \text{molecular mass}=2(23.0\frac{g}{mol})+32.0\frac{g}{mol}+4(16.0\frac{g}{mol})=142.0\frac{g}{mol}\)

\(\displaystyle \frac{\text{mass Na}}{\text{total mass}}=\frac{46.0\frac{g}{mol}}{142.0\frac{g}{mol}}=0.324\)

Convert the ratio to a percentage.

Example Question #25 : Stoichiometry And Analytical Chemistry

Which of the following samples contains a larger mass of hydrogen?

\(\displaystyle 350g\ HCN\)

\(\displaystyle 129g\ CH_2O\)

Possible Answers:

\(\displaystyle 129g\ CH_2O\)

\(\displaystyle 350g\ HCN\)

We must know the density of each compound in order to solve

The samples contain equal amounts of hydrogen

Correct answer:

\(\displaystyle 350g\ HCN\)

Explanation:

Start by calculating the percentages of hydrogen in each compound by using molar mass ratios.

\(\displaystyle \frac{1.0 \frac{g}{mol} H}{27.0 \frac{g}{mol} HCN} * 100 = 3.7 %\)

\(\displaystyle \frac{2.0 \frac{g}{mol} H}{30.0 \frac{g}{mol} CH_{2}O} * 100 = 6.7 %\)

Next, take the percentages of the given sample masses to determine the total mass of hydrogen in each.

\(\displaystyle 350 g HCN * \frac{3.7 g H}{100 g HCN} = 13.0 g H\)

\(\displaystyle 129 g CH_{2}O *\frac{6.7 g H}{100 g CH_{2}O} = 8.6 g H\)

We see that there is a larger mass of hydrogen in the hydrogen cyanide sample.  

Example Question #23 : Stoichiometry And Analytical Chemistry

How many grams of nitrogen are in 50g of ammonium sulfate?

Possible Answers:

5.9g

10.6g

5.3g

12.3g

11.6g

Correct answer:

10.6g

Explanation:

First convert grams of ammonium sulfate to moles, then use the mole-to-mole ratio between nitrogen and ammonium sulfate. Finally, convert moles of nitrogen back into grams.\(\displaystyle \small 50g(NH_{4})_{2}SO_{4}*\frac{1mol(NH_{4})_{2}SO_{4}}{132g(NH_{4})_{2}SO_{4}}*\frac{2mol N}{1mol(NH_{4})_{2}SO_{4}}*\frac{14g N}{1mol N}=10.6g\)

Example Question #27 : Stoichiometry And Analytical Chemistry

What is the molecular weight of NaCl? 

Molar mass of Na = 23g/mol

Molar mass of Cl = 35.5g/mol

Possible Answers:

58.5amu

58.5amu/mol

58.5g/amu

58.5g/mol

Correct answer:

58.5amu

Explanation:

To find the molecular weight (mass) of a molecule, simply add up the atomic weights of each atom within the molecule. The units used will be amu (atomic mass units) for molecular weight and g/mol for molar mass.

Example Question #24 : Stoichiometry And Analytical Chemistry

Convert 23g of water to moles.

Possible Answers:

1.4mol

1.3mol

2.6mol

0.8mol

Correct answer:

1.3mol

Explanation:

First find the molar mass of water (H2O). You should be comfortable with the molar masses of hydrigen and oxygen from memory to reduce time on the MCAT exam.

\(\displaystyle Molar\ mass=2(1\frac{g}{mol})+16\frac{g}{mol}=18\frac{g}{mol}\)

Next, solve for moles.

\(\displaystyle 23g*\frac{1mol}{18g}=1.28mol\)

Example Question #23 : Stoichiometry And Analytical Chemistry

Calculate the mass percent of sulfur in sulfuric acid \(\displaystyle (H_2SO_4)\).

\(\displaystyle S=32amu\)

\(\displaystyle O=16amu\)

\(\displaystyle H=1amu\)

Possible Answers:

\(\displaystyle 16\%\)

\(\displaystyle 46\%\)

\(\displaystyle 60\%\)

\(\displaystyle 20\%\)

\(\displaystyle 33\%\)

Correct answer:

\(\displaystyle 33\%\)

Explanation:

To calculate the mass percent, calculate the the individual masses of each element. Then divide the mass of sulfur by the total mass of the molecule. Since there is only one sulfur atom in sulfuric acid, the mass of sulfur in one atom is \(\displaystyle 32amu\).

\(\displaystyle (2\cdot1amu)+(1\cdot 32amu)+(4\cdot 16amu) = 98amu\)

\(\displaystyle \frac{32amu}{98amu}\cdot 100\%=33\%\)

Example Question #25 : Stoichiometry And Analytical Chemistry

Compounds can be distinguished from each other by using their molecular weights. The molecular weight of a compound depends on the individual atomic weights of the elements and the amount of each element present in the compound. Consider hexane for example. Hexane has a molecular formula of \(\displaystyle C_6H_1_4\). This means that it has 6 carbon atoms and 14 hydrogen atoms. To calculate the molecular weight of hexane, we can simply look up the molecular weight of carbon and hydrogen from the periodic table, multiply each molecular weight by the number of atoms (6 for carbon and 14 for hydrogen), and sum the two numbers. The molecular weight of an element is always given in \(\displaystyle \frac{grams}{moles}\). One mole is the defined as the number of atoms in twelve grams of carbon-12.

A researcher is trying to determine the molecular formula of a hydrocarbon molecule. He measures the molecular weight to be \(\displaystyle 126.24\frac{g}{mol}\). He also observes that the molecule has one \(\displaystyle \pi\) bond. What is the ratio of the number of carbon to hydrogen atoms in this molecule?

Possible Answers:

\(\displaystyle 1:3\)

\(\displaystyle 8:18\)

\(\displaystyle 9:20\)

\(\displaystyle 1:2\)

Correct answer:

\(\displaystyle 1:2\)

Explanation:

The empirical formula for hydrocarbon is \(\displaystyle C_nH_2_n_+_2\), where \(\displaystyle n\) is the number of carbons. This is only true if the hydrocarbon has no \(\displaystyle \pi\) bonds or ring structures. The question states that there is one \(\displaystyle \pi\) bond; therefore, the hydrocarbon will lose two hydrogen atoms (\(\displaystyle C_nH_2_n\)). Note that for every \(\displaystyle \pi\) bond and every ring the hydrocarbon is associated with the loss of two hydrogen atoms. If we calculate the molecular weight of hydrocarbons with different \(\displaystyle n\) values (\(\displaystyle C_nH_2_n\)) we will find that the nine-carbon hydrocarbon (with \(\displaystyle \pi\) bond), nonene, has a molecular weight of \(\displaystyle 126.24\frac{g}{mol}\). The molecular formula for nonene is \(\displaystyle C_9H_1_8\); therefore, the ratio of carbons to hydrogens is 9:18 or 1:2.

You can also calculate the ratio by simply looking at the empirical formula of this molecule (\(\displaystyle C_nH_2_n\)). There will be twice as many hydrogen atoms as carbon atoms; therefore, ratio of carbon to hydrogen will be 1:2.

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