Organic Chemistry : Organic Functional Groups and Molecules

Study concepts, example questions & explanations for Organic Chemistry

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Example Questions

Example Question #11 : Identifying Aromatic Compounds

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Assuming that this molecule is planar, determine whether this molecule is aromatic, and name the number of  electrons ( molecular orbitals).

Possible Answers:

Non aromatic, 6  electrons

Not aromatic, 8  electrons

Aromatic, 6  electrons

Aromatic, 8  electrons

Correct answer:

Not aromatic, 8  electrons

Explanation:

There is no p orbital surrounding the Boron atom, so the ring does not have a fully conjugated pi system. In addition, there are 8  electrons, which does not follow Huckel's rule (an aromatic system contains 4n+2 electrons). The pi electrons include the lone pair (not shown, but implicit) on the nitrogen atom, which is why the answers with "6 electrons" are not correct.

Example Question #12 : Organic Functional Groups

1

Assuming that this molecule is planar, determine whether this molecule is aromatic, and name the number of  electrons (not  molecular orbitals). 

Possible Answers:

Not aromatic, 8  electrons.

Aromatic, 6  electrons. 

Not aromatic, 6  electrons. 

Aromatic, 8  electrons.

Correct answer:

Aromatic, 6  electrons. 

Explanation:

The lone pairs on the two nitrogen atoms reside in sp2 orbitals, meaning they do not participate in resonance. Within the ring, there are three  bonds, meaning there are six  electrons. Thus, the molecule is aromatic because it is planar and follows Huckel's rule. 

Example Question #1 : Identifying Carbonyl Compounds

Identify the given organic functional group.

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Possible Answers:

Ester

Ketone

Acid anhydride

Carboxylic acid

Aldehyde

Correct answer:

Aldehyde

Explanation:

Aldehydes are carbonyls with one R-group and one hydrogen attached to the carbonyl carbon.

Example Question #2 : Identifying Carbonyl Compounds

Identify the given organic functional group.

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Possible Answers:

Ester

Acetal

Ketone

Carboxylic acid

Aldehyde

Correct answer:

Ketone

Explanation:

Ketones are carbonyls with two R-groups attached the the carbonyl carbon.

Example Question #3 : Identifying Carbonyl Compounds

Identify the given organic functional group.

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Possible Answers:

Ester

Carboxylic acid

Acid anhydride

Amide

Acid halide

Correct answer:

Acid halide

Explanation:

This is an acid halide, were X is any halogen (group VII). They are the most reactive of all the carboxylic acid derivatives.

Example Question #4 : Identifying Carbonyl Compounds

Identify the given organic functional group.

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Possible Answers:

Ester

Acid anhydride

Carboxylic acid

Ketone

Aldehyde

Correct answer:

Carboxylic acid

Explanation:

Carboxylic acids are composed of one R goup and a hydroxy group bound to the carbonyl carbon. The hydroxyl group gives the molecule acidic properties.

Example Question #5 : Identifying Carbonyl Compounds

Identify the given organic functional group.

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Possible Answers:

Acetal

Acid anhydride

Hemiketal

Ester

Aldehyde

Correct answer:

Hemiketal

Explanation:

This is a hemiketal. Hemiketals are formed from the reaction of a ketone with an alcohol. The alcohol attacks the carbonyl carbon, reducing the double bond and adding a hydroxyl group.

Example Question #181 : Organic Chemistry

Identify the given organic functional group.

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Possible Answers:

Acetal

Ketal

Acid anhydride

Hemiacetal

Hemiketal

Correct answer:

Ketal

Explanation:

Ketals have two -OR groups bound to a central carbon. The R groups attached to the oxygens are not necessarily the same. Ketals result from the reaction of a ketone with two equivalents of alcohol.

Example Question #182 : Organic Chemistry

Identify the given organic functional group.

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Possible Answers:

Acid anhydride

Ester

Acetal

Hemiacetal

Carboxylic acid

Correct answer:

Acid anhydride

Explanation:

Acid anhydrides are relatively reactive, since they have a fairly good leaving group (the conjugate base of a carboxylic acid) [COO-]. They are formed by reacting two carboxylic acids via dehydration synthesis.

Example Question #183 : Organic Chemistry

Identify the given organic functional group.

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Possible Answers:

Imine

Ester

Ether

Amine

Amide

Correct answer:

Amide

Explanation:

This is an amide. It is very unreactive since its leaving group is the conjugate base of an amine [HNR-]. 

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