MCAT Physical : MCAT Physical Sciences

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #801 : Mcat Physical Sciences

Which of the following adjustments would cause the equilibrium to shift towards the right?

I. Adding more substance B

II. Adding more substance D

III. Increasing the temperature

IV. Decreasing the volume

Possible Answers:

I and II

I, II, and III

I, III, and IV

I only

Correct answer:

I only

Explanation:

We know that concentration, temperature, medium and catalyst all affect the direction and the rate of the reaction through the Le Chatelier's Principle, where a system tries to relieve stress when stress is being applied. In order to push the equilibrium towards the right, we need to increase volume, decrease temperature, increase concentration of A and B, and decrease the concentrations of C and D. In the choices provided, only roman numeral I provided a correction suggestion. By increasing temperature, the system would want to go to the side that does not produce heat (the left). By increasing the amount of D, it will tend to shift reaction away from the species being added. By decreasing the volume and thus increasing the pressure, the system would want to shift left towards the side with less moles of gas. 

Example Question #802 : Mcat Physical Sciences

Which of the following adjustments would shift the equilibrium towards the left? 

I. Placing the reaction vessel into an ice bath

II. Increasing the pressure in the reaction vessel

III. Increasing the amount of C and D

IV. Decreasing the amount of A and B

Possible Answers:

III, and IV 

I, II, and IV 

I, and III 

II, III, and IV 

Correct answer:

II, III, and IV 

Explanation:

The following will shift the equilibrium to the left:

  • decreased volume (increased pressure)
  • increased temperature
  • decreased amounts of A and B
  • increased amounts of D and C

Of the choices, all are correct except for Roman numeral I. Placing the vessel into an ice bath decreases the temperature of the equilibrium, and thus the system would want to shift towards the side that produces heat to replace the heat lost. 

Example Question #1 : Radioactive Decay

What is the product when  undergoes an alpha decay?

Possible Answers:

Correct answer:

Explanation:

Alpha decay is the loss of a helium atom from the original particle.

The number of protons is reduced by two, and the nuclear mass is reduced by four.

Example Question #1 : Radioactive Decay

Which type of nuclear decay is displayed below?

Possible Answers:

Alpha decay

Electron capture

Gamma decay

Beta decay

Positron emission

Correct answer:

Positron emission

Explanation:

Positron emission is when the nucleus ejects a positron, or positive equivalent of an electron. It is also known as decay.

Beta decay is when the nucleus ejects a beta particle (electron).

Alpha decay is when the nucleus ejects an alpha particle (helium nucleus).

Electron capture is when the nucleus caputres an electron from the inner most shell. This process converts a proton to a neutron.

Finally, gamma decay is when an excited nucleus emits gamma rays. Gamma rays have no mass or charge.

Example Question #2 : Radioactive Decay

If an atom of potassium undergoes a positron emission, what will be the daughter nucleus? 

Possible Answers:

Correct answer:

Explanation:

An emission of a positron is also known to be  decay. A positron emission can be viewed as a positron being ejected; therefore, when potassium undergoes a positron emission, the daughter nucleus will be argon (Ar) with the weight of 39.

To understand how the daughter nucleus was determined, create a positron emission reaction with potassium.

Example Question #11 : Nuclear Chemistry And Electrons

Which of the following best describes the missing component in the reaction above?

Possible Answers:

A neutron

A photon

A hydrogen nucleus

An electron

An alpha particle

Correct answer:

An electron

Explanation:

This is an example of beta decay because the atomic number increases (from 6 to 7). This means a neutron has decayed into a proton, which occurs by emitting an electron, .

Example Question #1 : Radioactive Decay

The half-life of a particular isotope of radium is 1600 years. If a sample of this isotope originally has a mass of 120g, how long would it take the mass of this isotope to decrease to 15g?

Possible Answers:

1600 years

3200 years

6400 years

4800 years

800 years

Correct answer:

4800 years

Explanation:

First note that 15g is 1/8 of the original 120-gram mass, so all but 1/8 of these radium nuclei have decayed. By definition, ½ of the nuclei decay during one half-life. So the number of nuclei remaining after n half-lives is . In this case, three half-lives have elapsed since, . The answer is 3 * 1600 = 4800 years.

Example Question #807 : Mcat Physical Sciences

Thorium, , emits an alpha particle as it decays. Which of the following nuclei emerges from the decay? 

Possible Answers:

Correct answer:

Explanation:

In alpha decay a helium nucleus, , is emitted. Since the total number of nucleons must be conserved, the atomic number of the parent nucleus must decrease by two, and the mass number must decrease by four. Here, the new atomic number is 90 - 2 = 88, and new mass number is 234 - 4 = 230. 

Example Question #808 : Mcat Physical Sciences

If gold, , emits a beta particle, what will be the resulting product? 

Possible Answers:

Correct answer:

Explanation:

When a nucleus ejects a beta particle, the element is undergoing beta decay. The ejection of a beta particle is equivalent to the ejection of an electron. When gold ejects an electron, , the product will be .

Example Question #809 : Mcat Physical Sciences

In the operation of nuclear reactors, engineers make use of substances known as neutron poisons. These are used to help store nuclear waste and slow nuclear reactions, but are also generated naturally in nuclear chain reactions as a by-product. This natural by-product can stop the desirable chain reaction present in a nuclear reactor used for power generation. 

For example, in nuclear power plants, U-235 is used as a fuel. U-235 absorbs a neutron, and subsequently generates neutrons (which power the chain reaction) and Xe-135. Xe-135 is a well-known neutron poison, and thus can impact the continued chain reaction of a nuclear power plant if it becomes over abundant during power generation. 

To help account for this, engineers have developed measurements to quantify the impact of Xe-135 on nuclear operations. For instance, the time during which there is an inability to start a reactor due to the buildup of Xe-135 is referred to as the precluded start-up time. Also, the amount of time that the reactor cannot override the effects of built up Xe-135 is called poison outage time. Perhaps the most important measure that engineers have developed is the neutron absorption capacity (σ), which is measured in units of barns and is a function of microscopic cross section. Xe-135 has a neutron absorption capacity of 2.00 * 106 barns, while another common poison, Sm-149, has a neutron absorption capacity of 74,500 barns.

Nuclear reactions, such as the one described above with uranium, emit energy in the form of radiation. A scientist is considering three different forms of radiation to generate power. Which of the following types of radiation is highest in energy?

Possible Answers:

Positron emission

Electron capture

Gamma radiation

Beta radiation

Alpha radiation

Correct answer:

Gamma radiation

Explanation:

Gamma radiation is a highly energetic form of radiation, and is the type of radiation emitted when antimatter and matter annhilate each other upon contact.

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