MCAT Physical : MCAT Physical Sciences

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #23 : Stoichiometry And Analytical Chemistry

How many grams of nitrogen are in 50g of ammonium sulfate?

Possible Answers:

11.6g

12.3g

10.6g

5.3g

5.9g

Correct answer:

10.6g

Explanation:

First convert grams of ammonium sulfate to moles, then use the mole-to-mole ratio between nitrogen and ammonium sulfate. Finally, convert moles of nitrogen back into grams.

Example Question #27 : Stoichiometry And Analytical Chemistry

What is the molecular weight of NaCl? 

Molar mass of Na = 23g/mol

Molar mass of Cl = 35.5g/mol

Possible Answers:

58.5amu

58.5amu/mol

58.5g/amu

58.5g/mol

Correct answer:

58.5amu

Explanation:

To find the molecular weight (mass) of a molecule, simply add up the atomic weights of each atom within the molecule. The units used will be amu (atomic mass units) for molecular weight and g/mol for molar mass.

Example Question #24 : Stoichiometry And Analytical Chemistry

Convert 23g of water to moles.

Possible Answers:

2.6mol

1.4mol

0.8mol

1.3mol

Correct answer:

1.3mol

Explanation:

First find the molar mass of water (H2O). You should be comfortable with the molar masses of hydrigen and oxygen from memory to reduce time on the MCAT exam.

Next, solve for moles.

Example Question #29 : Stoichiometry And Analytical Chemistry

Calculate the mass percent of sulfur in sulfuric acid .

Possible Answers:

Correct answer:

Explanation:

To calculate the mass percent, calculate the the individual masses of each element. Then divide the mass of sulfur by the total mass of the molecule. Since there is only one sulfur atom in sulfuric acid, the mass of sulfur in one atom is .

Example Question #25 : Stoichiometry And Analytical Chemistry

Compounds can be distinguished from each other by using their molecular weights. The molecular weight of a compound depends on the individual atomic weights of the elements and the amount of each element present in the compound. Consider hexane for example. Hexane has a molecular formula of . This means that it has 6 carbon atoms and 14 hydrogen atoms. To calculate the molecular weight of hexane, we can simply look up the molecular weight of carbon and hydrogen from the periodic table, multiply each molecular weight by the number of atoms (6 for carbon and 14 for hydrogen), and sum the two numbers. The molecular weight of an element is always given in . One mole is the defined as the number of atoms in twelve grams of carbon-12.

A researcher is trying to determine the molecular formula of a hydrocarbon molecule. He measures the molecular weight to be . He also observes that the molecule has one  bond. What is the ratio of the number of carbon to hydrogen atoms in this molecule?

Possible Answers:

Correct answer:

Explanation:

The empirical formula for hydrocarbon is , where  is the number of carbons. This is only true if the hydrocarbon has no  bonds or ring structures. The question states that there is one  bond; therefore, the hydrocarbon will lose two hydrogen atoms (). Note that for every  bond and every ring the hydrocarbon is associated with the loss of two hydrogen atoms. If we calculate the molecular weight of hydrocarbons with different  values () we will find that the nine-carbon hydrocarbon (with  bond), nonene, has a molecular weight of . The molecular formula for nonene is ; therefore, the ratio of carbons to hydrogens is 9:18 or 1:2.

You can also calculate the ratio by simply looking at the empirical formula of this molecule (). There will be twice as many hydrogen atoms as carbon atoms; therefore, ratio of carbon to hydrogen will be 1:2.

Example Question #31 : Molecular Weight, Molecular Formula, And Moles

Compounds can be distinguished from each other by using their molecular weights. The molecular weight of a compound depends on the individual atomic weights of the elements and the amount of each element present in the compound. Consider hexane for example. Hexane has a molecular formula of . This means that it has 6 carbon atoms and 14 hydrogen atoms. To calculate the molecular weight of hexane, we can simply look up the molecular weight of carbon and hydrogen from the periodic table, multiply each molecular weight by the number of atoms (6 for carbon and 14 for hydrogen), and sum the two numbers. The molecular weight of an element is always given in . One mole is the defined as the number of atoms in twelve grams of carbon-12.

How many atoms of oxygen are found in 1g of oxygen gas?

Possible Answers:

Correct answer:

Explanation:

To solve this question, we need to first convert grams to moles, then moles to atoms. The molecular weight (MW) of oxygen gas,  is

The amount of moles in 1g of oxygen gas is

There are  atoms in  (this is called the Avogadro’s number); therefore, the number of atoms in  of  is

Example Question #31 : Stoichiometry And Analytical Chemistry

Compounds can be distinguished from each other by using their molecular weights. The molecular weight of a compound depends on the individual atomic weights of the elements and the amount of each element present in the compound. Consider hexane for example. Hexane has a molecular formula of . This means that it has 6 carbon atoms and 14 hydrogen atoms. To calculate the molecular weight of hexane, we can simply look up the molecular weight of carbon and hydrogen from the periodic table, multiply each molecular weight by the number of atoms (6 for carbon and 14 for hydrogen), and sum the two numbers. The molecular weight of an element is always given in . One mole is the defined as the number of atoms in twelve grams of carbon-12.

Consider two carbohydrates A and B. Molecule A is a 6-carbon carbohydrate and has twice as much molecular weight as molecule B. What can you conclude about molecule B?

Possible Answers:

None of these

Molecule B has twice as many oxygen atoms as molecule A

Molecule A has twice as many oxygen atoms as carbon atoms

Oxygen contributes to about  of the molecular weight of both molecules A and B

Correct answer:

Oxygen contributes to about  of the molecular weight of both molecules A and B

Explanation:

The empirical formula for carbohydrates is , where  is the number of carbon atoms. The question states that molecule A has 6 carbons; therefore,  and the molecular formula for molecule A is . The molecular weight (MW) of this compound is calculated using the molecular weight of each atom. The MW of each atom is obtained from the periodic table and is multiplied by the number atoms.

So, the molecular weight of molecule A is . Since it is also a carbohydrate, molecule B will have the same empirical formula as molecule A. Molecule B has half the molecular weight of molecule A; therefore, molecule B must have half the atoms as molecule A. The molecular formula of molecule B is . Note that MW of  is .

The MW contribution of oxygen to each compound is calculated as follows.

%MW of oxygen for molecule A = 

%MW of oxygen for molecule B =  

Therefore, oxygen contributes to 53% of MW in both compounds.

Example Question #1 : Reaction Calculations And Limiting Reagent

What products will be formed by the reaction between copper (II) fluoride and sodium sulfate?

Possible Answers:

Cu2Na and F2SO4

CuS and NaF

Cu2SO4 and NaF

CuSO4 and NaF

Correct answer:

CuSO4 and NaF

Explanation:

Recognize that this is a double replacement reaction in which ion pairs will switch. After reaction, copper (II) will now be paired with sulfate, and sodium with flouride according to the (unbalanced) equation below. Remember that sulfate has a charge of -2, and flouride of -1.

Example Question #1 : Reaction Calculations And Limiting Reagent

Which represents the correct balanced equation for the reaction between silver (I) nitrate and magnesium hydroxide?

Possible Answers:

Correct answer:

Explanation:

Silver (I) nitrate is AgNO3. Recognizing this allows us to eliminate two answer choices, which incorrectly substitute nitrogen (N) for nitrate (NO3) or balance the molecular charges incorrectly. Of the two remaining choices, only one is balanced correctly.  

Example Question #3 : Reaction Calculations And Limiting Reagent

Hydrogen can be produced on a large scale by a method called the Bosch process, by which steam is passed over heated iron shavings. The reaction is shown below:

 

Alternatively, hydrogen can be produced by reacting steam with natural gas, according to the following equation:  

How many molecules of carbon monoxide are produced per liter of hydrogen, when using the natural gas method of production at STP?

Possible Answers:

Correct answer:

Explanation:

Since the reaction takes place at STP, we can convert liters of hydrogen to moles using a constant.

Using this value, we can find the moles of carbon monoxide produced and convert to molecules by using Avogadro's number.

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